Rihanna and Chris Brown looked inseparable at The Grammy Awards on Feb. 10 but the couple is rumored to be may be calling it quits after a recent incident.

Daily Mail reported that the duo both arrived at the Playhouse Nightclub in Los Angeles on Wednesday night. Brown reportedly showed up at around midnight with a 20-person entourage and Rihanna, who did not know he was there, showed up half an hour later.

VIP hosts asked The Nobody's Business singer if she wanted to be seated with her boyfriend, but she declined and demanded to be moved elsewhere.

"Rihanna refused to sit with or even near Chris, and when Chris noticed she was there, he made a huge show of rubbing his presence her face," the source said. "He promptly ordered three more bottles of ace of spades which came out with in a procession of sparklers and scantily clad cocktail waitresses, causing a spectacle, which he clearly wanted Rihanna to see."

The two were at the club to celebrate Popular Demand's one year anniversary but never spoke to each other during the evening as they sat across the room from each other. Brown left the club around 2.15 a.m. in a grey Lamborghini, wearing his hoodie over his hat. Rihanna left about 45 minutes later.

Although Rihanna has publicly admitted she is back in a relationship with Brown in an interview with Rolling Stone, the couple did not spend Valentine's together.

According to E!, Rihanna celebrated Valentine's Day partying with friends at Blok nightclub Thursday in Los Angeles, with no sight of Brown.

"Happy Valentines Day," Rihanna tweeted to her 28 million followers earlier on Thursday. "Today the day fa lovin not hatin so to cats like you and I it's just another day..."

As for Valentine's gifts, she shared an Instagram picture revealing a bouquet from an unidentified admirer.

"Roses are green!" she wrote beneath a photo of what appeared to be a marijuana tree, "Somebody knows how to make me happy."

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Chris Brown, Rihanna