Are Brad Pitt and Jennifer Aniston about to come face-to-face on live television? Are Brad Pitt and Jennifer Aniston about to come face-to-face on Jimmy Kimmel Live? According to a new report, Jimmy Kimmel is hoping to reunite the former couple, who were married from 2000 to 2005, during a joint interview on his long-running late night talk show and the chances of the interview actually happening are “pretty good.