On Hollywood's biggest night, there is no better accessory than the one you love (the baby bump is a close second), and the celebrity couples did not disappoint at the 86th Academy Awards.

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The Oscars, hosted by the hilarious Ellen Degeneres, were extraordinarily star-studded this year. As newcomers like Lupita Nyong'o brought their family members with them to walk the carpet, fans were just as happy to see their favorite celebrities with their significant others to end the 2014 awards season. The couples who walked the carpet flawlessly made topping the best dressed list a joint effort.

Matthew McConaughey and his gorgeous wife Camila Alves complemented each other perfectly, as the parents of four appeared on the red carpet. Camila wore an old-Hollywood inspired peach gown, with a cape to cover her dainty shoulders. Best Actor nominee, McConaughey, wore a tailored white blazer with a black vest and pants.

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John Legend and Chrissy Teigen smiled and mingled with reporters as they walked down the red carpet. Legend, who is set to perform after the Oscars, wore a fitted black suit coupled with white diamond cufflinks by Gentleman Collection by David Thomas and Jason of Beverly Hills. Sports Illustrated cover model Chrissy Teigen turned heads in a floral, strapless Monique Lhuillier gown and Jimmy Choo shoes.

Olivia Wilde sported two major accessories as her baby bump and her fiancé Jason Sudekis accompanied her on the red carpet tonight. Sudeikis, who presented tonight, wore a Prada suit while the 7-months-pregnant Wilde wore a black Maison Valentino gown.

Angelina Jolie and Brad Pitt, arguably the most stunning couple the Oscars (and probably the world) have ever seen, were a vision of perfection at the 86th Academy Awards. Jolie wore a jaw-dropping Elie Saab Haute Couture beaded, metallic gown. Brad Pitt, attending for his work in 12 Years A Slave, wore a black tuxedo and his face. He does not really need anything else.

Finally, Will Smith and Jada Pinkett-Smith came out to support their fellow colleagues in film, making one of their first red carpet appearances of 2014. Jada wore a coral custom Versace gown, while Will wore a black Berluti suit and sported a new beard. The 45-year-old Oscar nominee presented the Best Picture Award, tonight.

Who is your favorite celebrity couple? Tell Enstars, here.

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Oscars 2014, Brad pitt and angelina jolie